論文名 | Spirostomin, Defense Toxin of the Ciliate Spirostomum teres : Isolation, Structure Elucidation, and Synthesis |
著者名 | |
著者名(別言語) | 世良, 佳彦 / / 土江, 松美 / / 三宅, 章雄 / 臼杵, 克之助 / 飯尾, 英夫 |
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抄録・内容(英) | The defense toxins, spirostomins A and B, have been isolated as a diastereomeric mixture from the ciliate microorganism Spirostomum teres. The structure of spirostomin was elucidated through a number of NMR experiments which allowed assigning the unprecedented spiro[(2,5-dimethyl-5,6,7,8-tetrahydronaphthalene-1,4-dione)-8,6'-(pyrane-2',5'-dione)] skeleton to this natural compound. The total syntheses of the racemic spirostomins confirmed their structure and relative configurations.
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備考 | This work was supported in part by a Grand-in Aid for Scientific Research (Grand no. 16310154) from the Ministry of Education, Science, Culture and Sports of Japan. |
言語 | eng |
ページ開始 | 633 |
ページ終了 | 635 |
著者版フラグ | author |
著者所属(英) | Osaka City University / Osaka City University / Osaka City University / University of Camerino, University of Macerata / University of Camerino / Osaka City University / Osaka City University |
3人目の著者情報 : KAKEN | |
3人目の著者情報 : その他 | |
4人目の著者情報 : その他 | |
6人目の著者情報 : KAKEN | |
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収録物名 | |
巻 | |
号 | |
刊行年月 | 2015 |
出版社 | Chemical Society of Japan |
ISSN | 1348-0715 |
雑誌書誌ID(NII) | AA12179675 ![CiNii.jpg](images/G0000438repository/csv_edit/linkage/CiNii.jpg) |
資料種別 | |
資料種別(英語) | Journal Article |
DOI | https://doi.org/10.1246/cl.150044 |
権利 | © 2015 The Chemical Society of Japan. This article may be downloaded for personal use only. Any other use requires prior permission of The Chemical Society of Japan. The following article has been submitted to ‘Chemistry Letters’. After it is published, it will be found at https://doi.org/10.1246/cl.150044 |
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